A new diphosphate Ba2LiGa(P2O7)2: synthesis, crystal structure and Eu3+-activated fluorescence performance

Author:

Li Y. N.1234,Zhao D.1234ORCID,Zhang R. J.1234,Li F. F.1234,Shi L. Y.1234,Yao Q. X.56784,Han X. Y.1234,Cui X. Q.1234

Affiliation:

1. College of Chemistry and Chemical Engineering

2. Henan Polytechnic University

3. Jiaozuo

4. China

5. School of Chemistry and Chemical Engineering

6. and Shandong Provincial Key Laboratory/Collaborative Innovation Center of Chemical Energy Storage and Novel Cell Technology

7. Liaocheng University

8. Liaocheng

Abstract

This work presents a new diphosphate Ba2LiGa(P2O7)2 with an anionic [LiGa(P2O7)2] framework that is constructed from P2O7, LiO5 and GaO6 groups. Eu3+-doped Ba2−xLiGa(P2O7)2:xEu3+ (x = 0.05–0.3) samples show intense red photoluminescence emission.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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