Cations mediating proton conductivity in an oxalate based microporous coordination polymer-Reference-Cited by-同舟云学术

Cations mediating proton conductivity in an oxalate based microporous coordination polymer

Published:2019 Issue:1 Volume:43 Page:24-27
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Meng Xing¹²³⁴⁵^ORCID,Wang Hai-Ning¹²³⁴⁵,Wang Xiao-Kun⁶⁷⁸⁹¹⁰,Dong Long-Zhang⁶⁷⁸⁹¹⁰^ORCID,Zou Yan-Hong¹²³⁴⁵

Affiliation:

1. School of Chemistry and Chemical Engineering

2. Shandong University of Technology

3. Zibo

4. Shandong, 255049

5. P. R. China

6. Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials

7. Jiangsu, Key Laboratory of New Power Batteries

8. College of Chemistry and Materials Science

9. Nanjing Normal University

10. Nanjing 210023

Abstract

Through cation substitution in a zirconium based coordination polymer, an isostructural framework 1@NH₄⁺ has been prepared without any apparent structural change. The proton conductivity of 1@NH₄⁺ is successfully improved. It exhibits high proton conductivity (1.39 × 10⁻² S cm⁻¹) at 98% relative humidity and 60 °C.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/NJ/C8NJ04763D

Reference28 articles.

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3. Multifunctional luminescent Zn(ii)-based metal–organic framework for high proton-conductivity and detection of Cr3+ ions in the presence of mixed metal ions