Efficient copolymerization of ethylene with norbornene or its derivatives using half-metallocene zirconium(iv) catalysts-Reference-Cited by-同舟云学术

Efficient copolymerization of ethylene with norbornene or its derivatives using half-metallocene zirconium(iv) catalysts

Published:2016 Issue:64 Volume:6 Page:59590-59599
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Li Yulian¹²³⁴⁵,Yang Jixing¹²³⁴⁵,Wang Bin¹²³⁴⁵,Li Yuesheng¹²³⁴⁵

Affiliation:

1. Tianjin Key Lab Composite & Functional Materials

2. School of Materials Science and Engineering

3. Tianjin University

4. Tianjin 300072

5. China

Abstract

Four [O,P]ZrCpCl₂ were synthesized, and showed good performance on regioselective ethylene/cyclic dienes copolymerizations. Comonomer incorporations up to 76% (ENB) and 40.6% (VNB), respectively, with activities above 10³ kg per mol_Zr per h can be achieved.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA11501B

Reference60 articles.

1. Chem. Eng. News, 2007, 85(24), 17

2. Metallocene catalyzed ethene- and propene co-norbornene polymerization: Mechanisms from a detailed microstructural analysis

3. Ethylene/Polar Monomer Copolymerization Behavior of Bis(phenoxy–imine)Ti Complexes: Formation of Polar Monomer Copolymers