Visible-light excited luminescent trigonal prismatic metallocages from a template-directed assembly

Author:

Xu Jian-Ping1234,Zou Wen1234,Zhan Shun-Ze12345ORCID,Zheng Ji56784ORCID,Wu Kun56784ORCID,Zhang Guo-Hui1234,Li Jing-Hong1234ORCID,Li Mian1234ORCID,Ning Guo-Hong56784ORCID,Li Dan56784ORCID

Affiliation:

1. Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province

2. Shantou University

3. Shantou 515063

4. P. R. China

5. College of Chemistry and Materials Science

6. and Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications

7. Jinan University

8. Guangzhou 510632

Abstract

Trigonal prismatic metallocages based on Cu3Pz3 and Cu2I2/Cu2Br2 with 24-component were assembled via a template-directed strategy. They showed rare visible-light responsive red emissions based on Cu2I2/Cu2Br2 coordination chromophores.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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