Photo-oxidative degradation of methylammonium lead iodide perovskite: mechanism and protection

Author:

Ouyang Yixin1234,Li Yajuan56784,Zhu Pengchen910111213,Li Qiang1234,Gao Yuan910111213,Tong Jianyu1412151613,Shi Li1234,Zhou Qionghua1234,Ling Chongyi1234ORCID,Chen Qian1234ORCID,Deng Zhengtao1412151613ORCID,Tan Hairen910111213,Deng Weiqiao56784ORCID,Wang Jinlan1234ORCID

Affiliation:

1. School of Physics

2. Southeast University

3. Nanjing 211189

4. China

5. State Key Laboratory of Molecular Reaction Dynamics

6. Dalian Institute of Chemical Physics

7. Chinese Academy of Sciences

8. Dalian 116023

9. National Laboratory of Solid State Microstructures

10. Collaborative Innovation Centre of Advanced Microstructures

11. Jiangsu Key Laboratory of Artificial Functional Materials

12. College of Engineering and Applied Sciences

13. Nanjing University

14. Department of Biomedical Engineering

15. Nanjing National Laboratory of Microstructures

16. Collaborative Innovation Center of Advanced Microstructures

Abstract

A new three-step photo-oxidative degradation mechanism of MAPbI3 is proposed. A strategy for protecting MAPbI3 by 2-(4-fluorophenyl)propan-2-amine modification is designed.

Funder

National Natural Science Foundation of China

Southeast University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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