Charge-transfer-energy-dependent oxygen evolution reaction mechanisms for perovskite oxides

Author:

Hong Wesley T.1234,Stoerzinger Kelsey A.1234,Lee Yueh-Lin5234,Giordano Livia52346,Grimaud Alexis5234,Johnson Alyssa M.7894,Hwang Jonathan1234ORCID,Crumlin Ethan J.1011124ORCID,Yang Wanli1011124,Shao-Horn Yang12345

Affiliation:

1. Department of Materials Science and Engineering

2. Massachusetts Institute of Technology

3. Cambridge

4. USA

5. The Research Laboratory of Electronics

6. Dipartimento di Scienza dei Materiali

7. Department of Mechanical Engineering

8. University of St. Thomas

9. St. Paul

10. Advanced Light Source

11. Lawrence Berkeley National Laboratory

12. Berkeley

Abstract

This work experimentally identifies the charge-transfer energy as a key factor governing the catalytic oxygen evolution reaction (OER) activity and mechanism across a wide range of perovskite chemistries.

Funder

National Science Foundation

Basic Energy Sciences

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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