Chemoselective formation of cyclo-aliphatic and cyclo-olefinic 1,3-diols via pressure hydrogenation of potentially biobased platform molecules using Knölker-type catalysts-Reference-Cited by-同舟云学术

Chemoselective formation of cyclo-aliphatic and cyclo-olefinic 1,3-diols via pressure hydrogenation of potentially biobased platform molecules using Knölker-type catalysts

Published:2021 Issue:29 Volume:50 Page:10102-10112
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

van Slagmaat Christian A. M. R.¹²³⁴⁵^ORCID,Faber Teresa⁴⁵⁶⁷³,Chou Khi Chhay⁴⁵⁶⁷³,Schwalb Freire Alfonso J.⁴⁵⁶⁷³,Hadavi Darya⁸⁶⁹³,Han Peiliang⁸⁶⁹³,Quaedflieg Peter J. L. M.¹²³¹⁰¹¹,Verzijl Gerard K. M.¹²¹³³,Alsters Paul L.¹²³¹⁰¹¹,De Wildeman Stefaan M. A.¹²³⁴⁵^ORCID

Affiliation:

1. Chemelot InSciTe

2. 6229 GS Maastricht

3. The Netherlands

4. Aachen-Maastricht Institute for Biobased Materials (AMIBM)

5. Faculty of Science and Engineering (FSE)

6. Maastricht University

7. Geleen

8. Maastricht MultiModal Molecular Imaging Institute (M4I)

9. 6229 ER Maastricht

10. InnoSyn B.V.

11. 6167 RD Geleen

12. Independent Scientist

13. Well

Abstract

Hemicellulose-derived five-membered cyclic ketones are strategic precursors for sustainable 1,3-diol building blocks, and bifunctional iron catalysts provide unprecedented chemoselectivity in hydrogenation toward aliphatic and olefinic structures.

Funder

European Regional Development Fund

Provincie Noord-Brabant

Ministerie van Economische Zaken

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT01252E

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