Are the current theories of electron transfer applicable to reactions in ionic liquids? An ESR-study on the TCNE/TCNE−˙ couple-Reference-Cited by-同舟云学术

Are the current theories of electron transfer applicable to reactions in ionic liquids? An ESR-study on the TCNE/TCNE−˙ couple

Published:2016 Issue:21 Volume:18 Page:14442-14448
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Mladenova B. Y.¹²³⁴,Kattnig D. R.⁵⁶⁷⁸,Sudy B.¹²³⁴,Choto P.⁹¹⁰¹¹,Grampp G.¹²³⁴

Affiliation:

1. Institute of Physical and Theoretical Chemistry

2. Graz University of Technology

3. A-8010 Graz

4. Austria

5. Physical and Theoretical Chemistry Laboratory

6. University of Oxford

7. Oxford

8. UK

9. Mae Fah Luang University

10. Chiang Rai

11. Thailand

Abstract

Electron transfer reactions in ionic liquids are profoundly affected by solvent properties. The activation barriers cannot be generally accounted for by Marcus' theory.

Funder

OeAD-GmbH

Austrian Academy of Sciences

Austrian Science Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP01750A

Reference78 articles.

1. Chapter 4. 3 EPR spectroscopy in room temperature ionic liquids

2. ESR-spectroscopy in ionic liquids: Dynamic linebroadening effects caused by electron-self exchange reactions within the methylviologene redox couple

3. Room-Temperature Ionic Liquids Discerned Via Nitroxyl Spin Probe Dynamics

4. Voltammetry in Room Temperature Ionic Liquids: Comparisons and Contrasts with Conventional Electrochemical Solvents.

5. Estimation of the rate constant for electron transfer in room temperature ionic liquids

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