Ionic liquid cations as methylation agent for extremely weak chalcogenido metalate nucleophiles-Reference-Cited by-同舟云学术

Ionic liquid cations as methylation agent for extremely weak chalcogenido metalate nucleophiles

Published:2019 Issue:20 Volume:10 Page:5211-5217
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Peters Bertram¹²³⁴⁵,Santner Silke¹²³⁴⁵,Donsbach Carsten¹²³⁴⁵,Vöpel Pascal⁶⁷⁸⁵,Smarsly Bernd⁶⁷⁸⁵^ORCID,Dehnen Stefanie¹²³⁴⁵^ORCID

Affiliation:

1. Fachbereich Chemie

2. Wissenschaftliches Zentrum für Materialwissenschaften (WZMW)

3. Philipps-Universität Marburg

4. 35043 Marburg

5. Germany

6. Physikalisch-Chemisches Institut

7. Justus-Liebig-Universität Gießen

8. 35392 Gießen

Abstract

Imidazolium-based ionic liquids served to selectively methylate terminal chalcogenide ligands of chalcogenidometalate clusters [Sn₁₀S₁₆O₄(SMe)₄]⁴⁻, [Mn₄Sn₄Se₁₃(SeMe)₄]⁶⁻, and [Hg₆Te₁₀(TeMe)₂]⁶⁻.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC01358J

Reference57 articles.

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3. Superbase Route to Supertetrahedral Chalcogenide Clusters

4. Synthesis of Crystalline Chalcogenides in Ionic Liquids

5. The Largest Supertetrahedral Oxychalcogenide Nanocluster and Its Unique Assembly

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