Light-induced water oxidation catalyzed by an oxido-bridged triruthenium complex with a Ru–O–Ru–O

Light-induced water oxidation catalyzed by an oxido-bridged triruthenium complex with a Ru–O–Ru–O–Ru motif

Published:2016 Issue:51 Volume:52 Page:8018-8021
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Tsubonouchi Yuta¹²³⁴⁵,Lin Shu¹²³⁴⁵,Parent Alexander R.⁶³⁴⁵,Brudvig Gary W.¹⁷⁸⁹,Sakai Ken¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Faculty of Sciences

3. Kyushu University

4. Fukuoka 819-0395

5. Japan

6. International Institute for Carbon-Neutral Energy Research (WPI-I2CNER)

7. Yale University

8. New Haven

9. USA

Abstract

A μ-oxido-bridged triruthenium complex (RuT2+), formed by air oxidation of a previously reported monoruthenium water-oxidation catalyst (WOC), serves as an efficient photochemical WOC with the turnover frequency (TOF) and turnover number (TON) 0.90 s⁻¹ and 610, respectively.

Funder

Ministry of Education, Culture, Sports, Science, and Technology

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC02816K

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