Molecular insights into chirality transfer from double axially chiral phosphoric acid in a synergistic enantioselective intramolecular amination-Reference-Cited by-同舟云学术

Molecular insights into chirality transfer from double axially chiral phosphoric acid in a synergistic enantioselective intramolecular amination

Published:2022 Issue:5 Volume:13 Page:1323-1334
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Tribedi Soumi¹^ORCID,Sunoj Raghavan B.¹^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 400076, India

Abstract

The origin of enantiocontrol in an intramolecular amination involving Pd(PPh3)4 and a double axially chiral phosphoric acid (DAPCy) dual catalytic system is traced to a more effective series of noncovalent interactions in the lower energy C–N bond formation transition state.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D1SC05749A

Reference74 articles.

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4. Catalyst-Controlled Stereoselective Synthesis of Atropisomers

5. Chiral Brønsted acids in enantioselective carbonyl activations – activation modes and applications

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