On chirality induction in the crystalline solid-containing sandwich-type [Ln(α-PW11O39)2]11− polyoxotungstate and proline-Reference-Cited by-同舟云学术

On chirality induction in the crystalline solid-containing sandwich-type [Ln(α-PW11O39)2]11− polyoxotungstate and proline

Published:2016 Issue:94 Volume:6 Page:91494-91507
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Iijima Jun¹²³⁴⁵,Naruke Haruo⁶⁷⁸⁵,Sanji Takanobu⁹⁷⁸⁵^ORCID

Affiliation:

1. Division of Chemistry

2. School of Medicine

3. Nihon University

4. Itabashi-ku

5. Japan

6. Chemical Resources Laboratory

7. Tokyo Institute of Technology

8. Yokohama

9. ERATO Iyoda Supra-integrated Material Project

Abstract

For the racemisation, the [Ln(α-PW₁₁O₃₉)₂]¹¹⁻ polyanion with light Ln experienced the ‘on-site rotation’ mechanism, while the [Ln(α-PW₁₁O₃₉)₂]¹¹⁻ polyanion with heavy Ln followed the “dissociation–association” mechanism.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA22278A

Reference31 articles.

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