Tri-coordinated zinc alkyl complexes with N^S/Se coordination of imino-phosphanamidinate chalcogenide ligands as precursors for efficient hydroboration of nitriles and esters-Reference-Cited by-同舟云学术

Tri-coordinated zinc alkyl complexes with N^S/Se coordination of imino-phosphanamidinate chalcogenide ligands as precursors for efficient hydroboration of nitriles and esters

Published:2024 Issue:25 Volume:53 Page:10592-10602
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Karmakar Himadri¹^ORCID,Kumar Gobbilla Sai¹^ORCID,Pal Kuntal²^ORCID,Chandrasekhar Vadapalli³⁴^ORCID,Panda Tarun K.¹^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Hyderabad, Kandi, Sangareddy 502284, Telangana, India

2. Department of Chemistry, University of Calcutta, 92, A.P.C. Road, Kolkata 700009, India

3. Tata Institute of Fundamental Research Hyderabad, Gopanpally, 500107, Hyderabad, India

4. Department of Chemistry, IIT Kanpur, Kanpur 208016, India

Abstract

A series of tri-coordinated zinc alkyl complexes with imino-phosphanamidinate chalcogenide ligands were prepared and utilized as catalysts in the hydroboration reaction of nitriles and esters to obtain N,N-diborylamines and boronate esters.

Funder

Council of Scientific and Industrial Research, India

Department of Science and Technology, Ministry of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00840E

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