Substitution of the laser borane anti-B18H22 with pyridine: a structural and photophysical study of some unusually structured macropolyhedral boron hydrides

Author:

Londesborough Michael G. S.123ORCID,Dolanský Jiří12345ORCID,Jelínek Tomáš12367,Kennedy John D.12389,Císařová Ivana45103,Kennedy Robert D.8911,Roca-Sanjuán Daniel121314ORCID,Francés-Monerris Antonio121314ORCID,Lang Kamil123ORCID,Clegg William15161711ORCID

Affiliation:

1. Institute of Inorganic Chemistry of the Czech Academy of Sciences

2. Husinec-Řež

3. Czech Republic

4. Charles University in Prague

5. Department of Inorganic Chemistry

6. Katchem s.r.o.

7. 278 01 Kralupy nad Vltavou

8. The School of Chemistry of the University of Leeds

9. Leeds

10. 128 43 Prague 2

11. UK

12. Instituto de Ciencia Molecular

13. Universitat de València

14. València

15. Chemistry

16. The School of Natural and Environmental Sciences of Newcastle University

17. Newcastle upon Tyne

Abstract

One-step derivatization of the laser borane, anti-B18H22, with pyridine gives three uniquely structured macropolyhedral boranes with interesting photophysical properties.

Funder

Ministerio de Economía y Competitividad

Grantová Agentura České Republiky

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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