Boron avoids cycloalkane-like structures in the LinBnH2n series-Reference-Cited by-同舟云学术

Boron avoids cycloalkane-like structures in the LinBnH2n series

Published:2016 Issue:3 Volume:40 Page:2007-2013
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Vásquez-Espinal Alejandro¹²³⁴⁵^ORCID,Torres-Vega Juan J.⁶⁷⁸⁹,Alvarez-Thon Luis¹⁰²³⁴⁵,Fuentealba Patricio¹¹¹²⁴⁵¹³,Islas Rafael¹⁴²³⁴⁵,Tiznado William¹⁴²³⁴⁵

Affiliation:

1. Doctorado en Fisicoquímica Molecular

2. Facultad de Ciencias Exactas

3. Universidad Andres Bello

4. Santiago

5. Chile

6. Facultad de Ciencias Físicas

7. Universidad Nacional Mayor de San Marcos

8. Lima

9. Peru

10. Departamento de Ciencias Físicas

11. Departamento de Física

12. Universidad de Chile

13. Centro para el Desarrollo de la Nanociencia y Nanotecnologia

14. Departamento de Ciencias Químicas

Abstract

The stability of cycloalkane-like structures in the series Li_nB_nH_2n is analyzed using ab initio calculations. Neither of these cyclic species is energetically favored, contrary to what happens with aromatic lithium boron hydride rings.

Funder

Comisión Nacional de Investigación Científica y Tecnológica

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/NJ/C5NJ02051D

Reference68 articles.

1. Controlled homocatenation of boron on a transition metal

2. Analysis of Why Boron Avoids sp2 Hybridization and Classical Structures in the BnHn+2 Series

3. Three-Dimensional Aromaticity in Polyhedral Boranes and Related Molecules