Ion transport mechanism in anhydrous lithium thiocyanate LiSCN part II: frequency dependence and slow jump relaxation-Reference-Cited by-同舟云学术

Ion transport mechanism in anhydrous lithium thiocyanate LiSCN part II: frequency dependence and slow jump relaxation

Published:2022 Issue:34 Volume:24 Page:20198-20209
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Joos Markus¹^ORCID,Conrad Maurice²^ORCID,Moudrakovski Igor¹^ORCID,Terban Maxwell W.¹^ORCID,Rad Ashkan¹,Kaghazchi Payam³^ORCID,Merkle Rotraut¹^ORCID,Dinnebier Robert E.¹^ORCID,Schleid Thomas²^ORCID,Maier Joachim¹^ORCID

Affiliation:

1. Max Planck Institute for Solid State Research, Heisenbergstr. 1, 70569 Stuttgart, Germany

2. Institut für Anorganische Chemie, University of Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany

3. Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research, Materials Synthesis and Processing (IEK-1), 52425 Jülich, Germany

Abstract

A frequency dependent conductivity is observed for dry Li(SCN) with local ion hopping at high (ω1), and long-range motion at low frequencies (ω2). The ion transport mechanism of the mobile defect considering cation–anion coordination is discussed.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP01837C

Reference59 articles.

1. Ion transport mechanism in anhydrous lithium thiocyanate LiSCN Part I: ionic conductivity and defect chemistry

2. Rotating sulfate ion contribution to electrical conductivity in Li2SO4 and LiNaSO4?

3. Enhancement of cation mobility in some sulphate phases due to a paddle-wheel mechanism

4. Evidence for and against the paddle-wheel mechanism of ion transport in superionic sulphate phases

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