Visible-light-induced [4 + 2] cycloaddition of pentafulvenes by organic photoredox catalysis
Author:
Affiliation:
1. Faculty of Pharmaceutical Science
2. Tokyo University of Science
3. Noda-city
4. Japan
5. Graduate School of Environment and Information Sciences
6. Yokohama National University
7. Yokohama 240-8501
Abstract
We have developed thioxanthylium photoredox catalyzed [4 + 2] cycloaddition of pentafulvenes at room temperature under green light irradiation, which affords tetrahydrocyclopenta[b]chromenes with high regioselectivities.
Funder
Yokohama National University
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/OB/D0OB01151G
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4. Palladium catalysed [3 + 2]-annulation reaction of vinylcyclopropanes with pentafulvenes: synthesis of polysubstituted spiro[4,4]nona-6,8-dienes
5. Regioselective electrophilic substitutions of fulvenes with ethyl glyoxylate and subsequent Diels–Alder reactions
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