Stereoselective coordination: a six-membered P,N-chelate tailored for asymmetric allylic alkylation

Author:

Császár Z.1234,Farkas G.1234,Bényei A.5674,Lendvay G.89104,Tóth I.1234,Bakos J.1234

Affiliation:

1. Department of Organic Chemistry

2. University of Pannonia

3. H-8200 Veszprém

4. Hungary

5. Department of Physical Chemistry

6. University of Debrecen

7. H-4032 Debrecen

8. Institute of Materials and Environmental Chemistry

9. Hungarian Academy of Sciences

10. H-1117 Budapest

Abstract

Six-membered chelate complexes [Pd(1a–b)Cl2], (2a–b) and [Pd(1a–b)(η3-PhCHCHCHPh)]BF4, (3a–b) of P,N-type ligands 1a, ((2S,4S)-2-diphenyl-phosphino-4-isopropylamino-pentane) and 1b, ((2S,4S)-2-diphenyl-phosphino-4-methylamino-pentane) have been prepared.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference53 articles.

1. J. Bayardon and S.Jugé, P-Chiral Ligands, in Phosphorus(iii) Ligands in Homogeneous Catalysis: Design and Synthesis, ed. P. C. J. Kamer and P. W. N. M. van Leeuwen, John Wiley & Sons, Ltd, Chichester, UK, 2012

2. tert-Butanesulfinylphosphines: Simple Chiral Ligands in Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to Electron-Deficient Olefins

3. Combining planar and central chirality in ferrocene thiophosphine-sulfoxides

4. Design of chiral sulfoxide–Schiff base hybrids and their application in Cu-catalyzed asymmetric Henry reactions

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