Influence of support texture and reaction conditions on the accumulation and activity in the gas-phase aldol condensation of <i>n</i>-pentanal on porous silica-Reference-Cited by-同舟云学术

Influence of support texture and reaction conditions on the accumulation and activity in the gas-phase aldol condensation of n-pentanal on porous silica

Published:2022 Issue:11 Volume:7 Page:2445-2459
ISSN:2058-9883
Container-title:Reaction Chemistry & Engineering
language:en
Short-container-title:React. Chem. Eng.

Author:

Schörner Markus¹,Kämmerle Stefanie¹,Wisser Dorothea²,Baier Benjamin¹,Hartmann Martin²^ORCID,Thommes Matthias³,Franke Robert⁴⁵,Haumann Marco¹^ORCID

Affiliation:

1. Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Lehrstuhl für Chemische Reaktionstechnik (CRT), Egerlandstr. 3, 91058 Erlangen, Germany

2. Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Erlangen Center for Interface Research and Catalysis (ECRC), Egerlandstr. 3, 91058 Erlangen, Germany

3. Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Lehrstuhl für Thermische Verfahrenstechnik (TVT), Egerlandstr. 3, 91058 Erlangen, Germany

4. Evonik Operations GmbH, Paul-Baumann-Str. 1, D-45772 Marl, Germany

5. Ruhr-Universität Bochum, Lehrstuhl für Theoretische Chemie, Universitätsstr. 150, D-44780 Bochum, Germany

Abstract

Aldol condensation of n-pentanal can lead to pore blocking and hence transport limitations in supported liquid phase (SLP) catalysts. By careful texture optimization this effect can be minimized.

Funder

Deutsche Forschungsgemeinschaft

European Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Fluid Flow and Transfer Processes,Process Chemistry and Technology,Chemical Engineering (miscellaneous),Chemistry (miscellaneous),Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/RE/D2RE00143H

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