Bis(bipyridine) ruthenium(ii) bis(phosphido) metalloligand: synthesis of heterometallic complexes and application to catalytic (E)-selective alkyne semi-hydrogenation
Author:
Affiliation:
1. Department of Chemistry
2. Graduate School of Science
3. Osaka Prefecture University
4. Osaka 599-8531
5. Japan
Abstract
The first (bpy)2Ru(ii) phosphido complex serves as an effective bidentate metallophosphine ligand to generate catalytically active heterobimetallic species.
Funder
Japan Society for the Promotion of Science
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT04646H
Reference49 articles.
1. Synthesis, Structure, and Catalysis of Palladium Complexes Bearing a Group 13 Metalloligand: Remarkable Effect of an Aluminum-Metalloligand in Hydrosilylation of CO2
2. Rhodium Complexes Bearing PAlP Pincer Ligands
3. Tuning Nickel with Lewis Acidic Group 13 Metalloligands for Catalytic Olefin Hydrogenation
4. Modulating the σ-Accepting Properties of an Antimony Z-type Ligand via Anion Abstraction: Remote-Controlled Reactivity of the Coordinated Platinum Atom
5. Me2AlCH2PMe2: A New, Bifunctional Cocatalyst for the Ni(II)-Catalyzed Oligomerization of PhSiH3
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