Intermolecular interactions between σ- and π-holes of bromopentafluorobenzene and pyridine: computational and experimental investigations
Author:
Affiliation:
1. State Key Laboratory of Applied Organic Chemistry
2. Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province
3. College of Chemistry and Chemical Engineering
4. Lanzhou University
5. Lanzhou
Abstract
The σ- and π-holes of C6F5Br exhibiting positive electrostatic potentials make these sites favorably interact with the N atom and π ring of C5H5N with negative electrostatic potentials.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2018/CP/C8CP00420J
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5. Cooperativity between the Halogen Bond and the Hydrogen Bond in H3N⋅⋅⋅XY⋅⋅⋅HF Complexes (X, Y=F, Cl, Br)
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