Supramolecular-induced regiocontrol over the photochemical [4 + 4] cyclodimerization of NHC- or azole-substituted anthracenes

Author:

Bai Sha12345,Ma Li-Li12345,Yang Tao67895ORCID,Wang Fang12345,Wang Li-Feng12345,Hahn F. Ekkehardt10111213ORCID,Wang Yao-Yu12345ORCID,Han Ying-Feng12345ORCID

Affiliation:

1. Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education

2. College of Chemistry and Materials Science

3. Northwest University

4. Xi'an 710127

5. P. R. China

6. School of Science

7. MOE Key Laboratory for Non-Equilibrium Synthesis and Modulation of Condensed Matter

8. Xi'an Jiaotong University

9. Xi'an 710049

10. Institut für Anorganische und Analytische Chemie

11. Westfälische Wilhelms-Universität Münster

12. 48149 Münster

13. Germany

Abstract

A supramolecular templating strategy that enables the photochemical [4 + 4] cycloaddition of 2,6-difunctionalized anthracene derivatives with unique stereoselectivity has been developed based on metal-NHC units.

Funder

National Natural Science Foundation of China

Shaanxi Key Science and Technology Innovation Team Project

Northwest University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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