Regio- and stereoselective intermolecular carbolithiation reactions

Author:

Marsico G.1234ORCID,Scafato P.1234ORCID,Belviso S.1234ORCID,Superchi S.1234ORCID

Affiliation:

1. Dipartimento di Scienze

2. Università della Basilicata

3. Potenza

4. Italy

Abstract

Carbolithiation of alkenes provides a powerful tool for the construction of up to two novel carbon–carbon or carbon–heteroatoms bonds in a regio- and stereo-controlled manner. The synthetic potentiality of this reaction is highlighted.

Funder

Ministero dell’Istruzione, dell’Università e della Ricerca

Università degli Studi della Basilicata

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference80 articles.

1. Enantioselective carbometallation of unactivated olefins

2. P.Knochel , Carbometallation of Alkenes and Alkynes in Comprehensive Organic Synthesis , ed. B. M. Trost , Pergamon , Oxford , 1991 , vol. 4 , pp. 867–872

3. Synthetic applications of carbolithiation transformations

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