14-Electron Rh and Ir silylphosphine complexes and their catalytic activity in alkene functionalization with hydrosilanes-Reference-Cited by-同舟云学术

14-Electron Rh and Ir silylphosphine complexes and their catalytic activity in alkene functionalization with hydrosilanes

Published:2021 Issue:34 Volume:50 Page:11783-11792
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Abeynayake Niroshani S.¹,Zamora-Moreno Julio¹²,Gorla Saidulu¹,Donnadieu Bruno¹,Muñoz-Hernández Miguel A.¹,Montiel-Palma Virginia¹^ORCID

Affiliation:

1. Department of Chemistry, Mississippi State University, Box 9573, Mississippi State, Mississippi 39762, USA

2. Centro de Investigaciones Químicas-IICBA, Universidad Autónoma del Estado de Morelos, Av. Universidad 1001, Col. Chamilpa, Cuernavaca, Morelos 62209, Mexico

Abstract

14-electron Rh and Ir species as robust catalysts for silicon functionalization.

Funder

Mississippi State University

National Science Foundation

Consejo Nacional de Ciencia y Tecnología

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00677K

Reference53 articles.

1. First Stabilization of 14-Electron Rhodium(I) Complexes by Hemichelation

2. A Neutral Three-Coordinate Alkylrhodium(I) Complex: Stabilization of a 14-Electron Species by γ-C−H Agostic Interactions with a Saturated Hydrocarbon Group

3. Rhodium(I) Complexes of the Conformationally Rigid IBioxMe4 Ligand: Isolation of a Stable Low-Coordinate T-Shaped Complex

4. Alkyl dehydrogenation in a Rh(i) complex via an isolated agostic intermediate

5. Computational and Experimental Test of Steric Influence on Agostic Interactions: A Homologous Series for Ir(III)

Cited by 8 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. A Hybrid Benzothiazolyl-NHC Ligand with a Flexible −CH₂– Linker and Its Cationic Rh^(I) Complex That Catalyzes the Olefin Hydrosilylation;Organometallics;2024-04-16

2. Crafting Versatile Modes of Pt(II) Complexes with Flexidentate Pyridyl‐β‐diketones: Synthesis, Structural Characterization, and Catalytic Behavior in Olefin Hydrosilylation;ChemCatChem;2023-12-18

3. Air-Stable 14-Electron Rhodium(III) Complexes Bearing Si,N Ligands as Catalysts in Hydrolysis of Silanes;Organometallics;2023-10-12

4. Pt^II−N‐Heterocyclic Carbene Complexes in Solvent‐Free Alkene Hydrosilylation;Chemistry – A European Journal;2023-05-30

5. Cyclobutadiene platinum complex as a new type of precatalyst for hydrosilylation of alkenes and alkynes;Applied Organometallic Chemistry;2023-01-06