Chemoselective heterogeneous iridium catalyzed hydrogenation of cinnamalaniline

Author:

Savela Risto12345ORCID,Shcherban Nataliya D.6789ORCID,Melander Marko M.1011121314ORCID,Bezverkhyy Igor15161718ORCID,Simakova Irina L.192021ORCID,Långvik Otto12345ORCID,Kholkina Ekaterina12242314,Schindler Tamara12345,Krauβ Annabelle12345,Honkala Karoliina1011121314ORCID,Murzin Dmitry Yu.12242314ORCID,Leino Reko12345ORCID

Affiliation:

1. Johan Gadolin Process Chemistry Centre

2. Laboratory of Molecular Science and Technology

3. Organic Chemistry Research Group

4. Åbo Akademi University

5. FI-20500 Turku

6. L.V. Pisarzhevsky Institute of Physical Chemistry

7. National Academy of Sciences of Ukraine

8. Kiev

9. Ukraine

10. Department of Chemistry

11. Nanoscience Center

12. University of Jyväskylä

13. FI-40014 Jyväskylä

14. Finland

15. Laboratoire Interdisciplinaire Carnot de Bourgogne

16. UMR 6303 CNRS-Université de Bourgogne-Franche Comté

17. Dijon Cedex

18. France

19. Boreskov Institute of Catalysis

20. Novosibirsk

21. Russia

22. Laboratory of Industrial Chemistry and Reaction Engineering

23. Turku

Abstract

A selective atmospheric hydrogenation of unsaturated imines over heterogeneous iridium catalyst is described, in addition the selectivity is elucidated by DFT-calculations.

Funder

Russian Foundation for Basic Research

National Academy of Sciences of Ukraine

Luonnontieteiden ja Tekniikan Tutkimuksen Toimikunta

Ministry of Science and Higher Education of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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