Regulating the *OCCHO intermediate pathway towards highly selective photocatalytic CO2 reduction to CH3CHO over locally crystallized carbon nitride-Reference-Cited by-同舟云学术

Regulating the *OCCHO intermediate pathway towards highly selective photocatalytic CO2 reduction to CH3CHO over locally crystallized carbon nitride

Published:2022 Issue:1 Volume:15 Page:225-233
ISSN:1754-5692
Container-title:Energy & Environmental Science
language:en
Short-container-title:Energy Environ. Sci.

Author:

Liu Qiong¹,Cheng Hui¹^ORCID,Chen Tianxiang²^ORCID,Lo Tsz Woon Benedict²^ORCID,Xiang Zhangmin¹^ORCID,Wang Fuxian¹^ORCID

Affiliation:

1. Institute of Analysis, Guangdong Academy of Sciences (China National Analytical Center, Guangzhou), Guangzhou, Guangdong, 510070, China

2. State Key Laboratory of Chemical Biology and Drug Discovery, Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hong Kong, China

Abstract

Locally crystallized PCN is prone to form *OCCHO groups rather than *CH2O groups, regulating the endoergic C–C coupling step to a simultaneous exoergic reaction and changing the reaction pathway towards CH3CHO (selectivity of 98.3%) instead of HCHO.

Funder

China Postdoctoral Science Foundation

National Natural Science Foundation of China

Natural Science Foundation of Guangdong Province

Guangzhou Science and Technology Program key projects

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/EE/D1EE02073K

Reference58 articles.