Formation of a tetranuclear supramolecule via non-covalent Pb⋯Cl tetrel bonding interaction in a hemidirected lead(ii) complex with a nickel(ii) containing metaloligand-Reference-Cited by-同舟云学术

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Formation of a tetranuclear supramolecule via non-covalent Pb⋯Cl tetrel bonding interaction in a hemidirected lead(ii) complex with a nickel(ii) containing metaloligand

Published:2019 Issue:44 Volume:21 Page:6859-6868
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Mirdya Saikat¹²³⁴⁵,Frontera Antonio⁶⁷⁸⁹^ORCID,Chattopadhyay Shouvik¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Inorganic Section

3. Jadavpur University

4. Kolkata-700032

5. India

6. Departament de Química

7. Universitat de les Illes Balears

8. 07122 Palma de Mallorca

9. Spain

Abstract

A hetero-nuclear nickel(ii)/lead(ii) complex has been synthesized and characterized. The tetrel bonding interactions established between the σ-hole at the hemi-coordinated lead(ii) and the electron rich chlorido ligand has been analyzed by DFT study.

Funder

Council of Scientific and Industrial Research, India

Jadavpur University

Ministerio de Economía y Competitividad

Agencia Estatal de Investigación

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CE/C9CE01283D

Reference95 articles.

1. Unique example of a T3(2)4(2)3(2)6(2) water tape containing acetate–water hybrid hexamer in a heterometallic schiff base complex host

2. Unique example of a trigonal dodecahedral Na+ in a compartmental Schiff base N,N′-(1,2-Phenylene)-bis(3-methoxysalicylideneimine)

3. A combined experimental and computational study on supramolecular assemblies in hetero-tetranuclear nickel(ii)–cadmium(ii) complexes with N2O4-donor compartmental Schiff bases

4. Two new hetero-dinuclear nickel(II)/zinc(II) complexes with compartmental Schiff bases: Synthesis, characterization and self assembly

5. Anion mediated diversity in the H-bonded assembly of a series of heteronuclear copper(II)/sodium(I) compounds

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