Formation of a tetranuclear supramolecule via non-covalent Pb⋯Cl tetrel bonding interaction in a hemidirected lead(ii) complex with a nickel(ii) containing metaloligand

Author:

Mirdya Saikat12345,Frontera Antonio6789ORCID,Chattopadhyay Shouvik12345ORCID

Affiliation:

1. Department of Chemistry

2. Inorganic Section

3. Jadavpur University

4. Kolkata-700032

5. India

6. Departament de Química

7. Universitat de les Illes Balears

8. 07122 Palma de Mallorca

9. Spain

Abstract

A hetero-nuclear nickel(ii)/lead(ii) complex has been synthesized and characterized. The tetrel bonding interactions established between the σ-hole at the hemi-coordinated lead(ii) and the electron rich chlorido ligand has been analyzed by DFT study.

Funder

Council of Scientific and Industrial Research, India

Jadavpur University

Ministerio de Economía y Competitividad

Agencia Estatal de Investigación

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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