Rapid and precise determination of zero-field splittings by terahertz time-domain electron paramagnetic resonance spectroscopy

Author:

Lu Jian1234ORCID,Ozel I. Ozge5234,Belvin Carina A.5234,Li Xian1234,Skorupskii Grigorii1234,Sun Lei1234ORCID,Ofori-Okai Benjamin K.1234,Dincă Mircea1234ORCID,Gedik Nuh5234,Nelson Keith A.1234

Affiliation:

1. Department of Chemistry

2. Massachusetts Institute of Technology

3. Cambridge

4. USA

5. Department of Physics

Abstract

Single-cycle THz fields induce free-induction decays from high-spin transition-metal complexes, yielding THz EPR spectra and zero-field splitting parameters from a simple tabletop measurement.

Funder

National Science Foundation

Samsung

Office of Naval Research

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference40 articles.

1. Zero-field splitting in nickel(II) complexes: A comparison of DFT and multi-configurational wavefunction calculations

2. Zero-field splitting in metal complexes

3. Temperature Dependence of the Nitrogen-Vacancy Magnetic Resonance in Diamond

4. High Resolution EPR: Applications to Metalloenzymes and Metals in Medicine, ed. G. Hanson and L. J. Berliner, Springer, 2009

5. O. Kahn , Molecular magnetism, Wiley VCH, New York, USA, 1993

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