Rapid and precise determination of zero-field splittings by terahertz time-domain electron paramagnetic resonance spectroscopy
Author:
Affiliation:
1. Department of Chemistry
2. Massachusetts Institute of Technology
3. Cambridge
4. USA
5. Department of Physics
Abstract
Single-cycle THz fields induce free-induction decays from high-spin transition-metal complexes, yielding THz EPR spectra and zero-field splitting parameters from a simple tabletop measurement.
Funder
National Science Foundation
Samsung
Office of Naval Research
Basic Energy Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/SC/C7SC00830A
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