Hydroboration of isocyanates: cobalt-catalyzed <i>vs.</i> catalyst-free approaches-Reference-Cited by-同舟云学术

Hydroboration of isocyanates: cobalt-catalyzed vs. catalyst-free approaches

Published:2022 Issue:34 Volume:20 Page:6821-6830
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Gudun Kristina A.¹,Tussupbayev Samat²,Slamova Ainur³,Khalimon Andrey Y.¹⁴^ORCID

Affiliation:

1. Department of Chemistry, School of Sciences and Humanities, Nazarbayev University, 53 Kabanbay Batyr. Avenue, Nur-Sultan 010000, Kazakhstan

2. Institute of Polymer Materials and Technologies, 3/1 Atyrau 1, Almaty 050019, Kazakhstan

3. Core Facilities, Office of the Provost, Nazarbayev University, 53 Kabanbay Batyr. Avenue, Nur-Sultan 010000, Kazakhstan

4. The Environment and Resource Efficiency Cluster (EREC), Nazarbayev University, 53 Kabanbay Batyr. Avenue, Nur-Sultan 010000, Kazakhstan

Abstract

Selective hydroboration of isocyanates to formamides was demonstrated using a bench-stable and commercially available cobalt pre-catalyst. The deoxygenation of isocyanates to N-methylamines was performed under catalyst-free and solvent-free conditions.

Funder

Nazarbayev University

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/OB/D2OB01192A

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