Porous LiNi0.5Mn1.5O4 sphere as 5 V cathode material for lithium ion batteries
Author:
Affiliation:
1. State Key Lab of Physical Chemistry of Solid Surfaces
2. Department of Chemistry
3. Collaborative Innovation Center of Chemistry for Energy Materials
4. College of Chemistry and Chemical Engineering
5. Xiamen University
Abstract
A new type of microsized porous spherical LiNi0.5Mn1.5O4 (LNMO-Air) cathode material for a lithium ion secondary battery has been synthesized by an impregnation method using highly reactive nanocupule MnO2 spheres as the manganese source. These LNMO-Air spheres are aggregates of nanosized polyhedron particles with well-defined cubic spinel structure. They showed excellent rate capability and cycle stability, compared with other microspheres of LNMO.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/TA/C4TA02903H
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