Functionalization of o-carboranes via carboryne intermediates

Author:

Qiu Zaozao12ORCID,Xie Zuowei13ORCID

Affiliation:

1. Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Rd, Shanghai 200032, China

2. CAS Key Laboratory of Energy Regulation Materials, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Rd, Shanghai 200032, China

3. Department of Chemistry and State Key Laboratory of Synthetic Chemistry, The Chinese University of Hong Kong, Shatin, N. T, Hong Kong, China

Abstract

Carborynes, 3D analogues of benzyne, are a class of very useful synthons for the synthesis of a large variety of functionalized carboranes. This review provides a comprehensive overview of recent advances in this interesting research field.

Funder

National Natural Science Foundation of China

Research Grants Council, University Grants Committee

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference99 articles.

1. R. N.Grimes , Carboranes , Academic Press , Amsterdam , 3rd edn, 2016

2. N. S.Hosmane and R. D.Eagling , Handbook of Boron Science , World Scientific , 2018

3. Boron clusters in luminescent materials

4. Icosahedral boron clusters: a perfect tool for the enhancement of polymer features

5. Electrochemistry and Photoluminescence of Icosahedral Carboranes, Boranes, Metallacarboranes, and Their Derivatives

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