Phosphorescent platinum(ii) alkynyls end-capped with benzothiazole units
Author:
Affiliation:
1. Departamento de Química-Centro de Síntesis Química de La Rioja
2. (CISQ)
3. Universidad de La Rioja
4. Logroño
5. Spain
Abstract
Phosphorescent platinum(ii) alkynyls. Phosphorescent trans-bis(alkynyl) bis(phosphine) or bis(cyanide) PtII derivatives (1–4) based on the 2-phenylbenzothiazole unit have been prepared. The negative solvatochromic behavior of 4 has been analyzed by the Kamlet–Taft solvent scale and the Gutmann's acceptor numbers. The optical properties were addressed by TD and DFT calculations on 2 and 4.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT00029D
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