Calcium stilbene complexes: structures and dual reactivity-Reference-Cited by-同舟云学术

Calcium stilbene complexes: structures and dual reactivity

Published:2017 Issue:75 Volume:53 Page:10386-10389
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Causero Andrea¹²³⁴,Elsen Holger¹²³⁴,Ballmann Gerd¹²³⁴,Escalona Ana¹²³⁴,Harder Sjoerd¹²³⁴^ORCID

Affiliation:

1. Inorganic and Organometallic Chemistry

2. University Erlangen-Nürnberg

3. 91058 Erlangen

4. Germany

Abstract

Addition of a calcium hydride complex to diphenylacetylene gave a complex in which the stilbene dianion symmetrically bridges two Ca²⁺ions. With H₂, this complex reacts as a double Brønsted base. In reaction with I₂it provides two electrons.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C7CC05792J

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