Effect of internal oxygen substituents on the properties of bowl-shaped aromatic hydrocarbons

Author:

Takeo Yoshihiro1,Hirano Junichiro1,Shimizu Daiki2ORCID,Fukui Norihito13ORCID,Shinokubo Hiroshi1ORCID

Affiliation:

1. Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, and Integrated Research Consortium on Chemical Science (IRCCS), Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8603, Japan

2. Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan

3. PRESTO, Japan Science and Technology Agency (JST), Kawaguchi, Saitama 332-0012, Japan

Abstract

In this study, we compare a bowl-shaped aromatic hydrocarbon with internal methoxy groups to related derivatives with hydrogen, methyl, and anisyl groups, evaluating their electron-accepting properties, electronic absorption spectra, and fullerene-binding behavior.

Funder

Japan Society for the Promotion of Science

Precursory Research for Embryonic Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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