Phenylacetylene polymerisation mediated by cationic cyclometallated palladium(ii) complexes bearing benzylidene 2,6-diisopropylphenylamine and its derivatives as ligands-Reference-Cited by-同舟云学术

Phenylacetylene polymerisation mediated by cationic cyclometallated palladium(ii) complexes bearing benzylidene 2,6-diisopropylphenylamine and its derivatives as ligands

Published:2018 Issue:35 Volume:47 Page:12209-12217
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Joseph M. Cassiem.¹²³⁴⁵^ORCID,Swarts Andrew J.⁶⁷⁸⁹⁵^ORCID,Mapolie Selwyn F.¹²³⁴⁵^ORCID

Affiliation:

1. DST-NRF Centre of Excellence in Catalysis (c*change)

2. Department of Chemistry and Polymer Science

3. Stellenbosch University

4. 7601 Stellenbosch

5. South Africa

6. Catalysis and Synthesis Research Group

7. Focus Area for Chemical Resource Beneficiation

8. North-West University

9. Potchefstroom 2520

Abstract

Novel cationic palladacycle complexes of benzylidene-2,6-diisopropylphenylamine were found to be efficient catalyst precursors in the polymerization of phenylacetylene.

Funder

National Research Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT02728E

Reference41 articles.

1. Preparation and properties of polyacetylene membranes substituted with trifluoromethylated heterocyclic groups

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3. Poly[3,5-di-tert-butyl-4-[(2,4,6-tri-tert-butyl-phenyl)oxalato]phenylacetylene]: a photochemical precursor to a conjugated polyradical