A molecular electron density theory study of the [3 + 2] cycloaddition reaction of nitrones with strained allenes-Reference-Cited by-同舟云学术

A molecular electron density theory study of the [3 + 2] cycloaddition reaction of nitrones with strained allenes

Published:2017 Issue:43 Volume:7 Page:26879-26887
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Domingo Luis R.¹²³⁴^ORCID,Ríos-Gutiérrez Mar¹²³⁴^ORCID,Pérez Patricia⁵⁶⁷⁸⁹^ORCID

Affiliation:

1. Department of Organic Chemistry

2. University of Valencia

3. E-46100 Burjassot

4. Spain

5. Universidad Andres Bello

6. Facultad de Ciencias Exactas

7. Departamento de Ciencias Químicas

8. Millennium Nucleus Chemical Processes and Catalysis (CPC)

9. Santiago

Abstract

The molecular electron density theory study of this [3 + 2] cycloaddition reveals that the strain present in the cyclic allene changes its reactivity to that characteristic of highly reactive radical species.

Funder

Secretaría de Estado de Investigación, Desarrollo e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/RA/C7RA01916E

Reference61 articles.

1. Understanding the polar mechanism of the ene reaction. A DFT study

2. A DFT Study of Inter- and Intramolecular Aryne Ene Reactions

3. π-Strain-Induced Electrophilicity in Small Cycloalkynes: A DFT Analysis of the Polar Cycloaddition of Cyclopentyne towards Enol Ethers

4. A simple measure of electron localization in atomic and molecular systems

5. The Chemistry of Xylylenes. VII. Some Reactions of p-Xylylene that Occur via Cationic Intermediates2

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