Microwave-assisted solution polycondensation of l-lactic acid using a Dean–Stark apparatus for a non-thermal microwave polymerization effect induced by the electric field-Reference-Cited by-同舟云学术

Microwave-assisted solution polycondensation of l-lactic acid using a Dean–Stark apparatus for a non-thermal microwave polymerization effect induced by the electric field

Published:2014 Issue:18 Volume:5 Page:5283-5288
ISSN:1759-9954
Container-title:Polym. Chem.
language:en
Short-container-title:Polym. Chem.

Author:

Yamada Shinji¹²³⁴,Takasu Akinori¹²³⁴,Takayama Sadatsugu⁵⁶,Kawamura Kazuhiko⁷⁸

Affiliation:

1. Department of Frontier Materials

2. Graduate School of Engineering

3. Nagoya Institute of Technology

4. Nagoya 466-8555, Japan

5. National Institute for Fusion Science

6. Toki-city, Japan

7. Chubu Electric Power Co., Inc.

8. Nagoya 459-8522, Japan

Abstract

The solution polycondensation of l-lactic acid (l-LA) in xylene catalyzed by Sc(OTf)₃ was examined using a Dean–Stark apparatus under various microwave power conditions (100–400 W). The results indicate the existence of a non-thermal microwave effect induced by an electric field.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2014/PY/C4PY00639A

Reference34 articles.

1. Biodegradable polymers

2. Applications of life cycle assessment to NatureWorks™ polylactide (PLA) production

3. Direct dehydration polycondensation of lactic acid catalyzed by water-stable Lewis acids

4. Synthesis of Aliphatic Polyesters by Direct Polyesterification of Dicarboxylic Acids with Diols under Mild Conditions Catalyzed by Reusable Rare-Earth Triflate

5. Environmentally Benign Polyester Synthesis by Room Temperature Direct Polycondensation of Dicarboxylic Acid and Diol

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