Ring-expansion approach towards extended asymmetric benzopentafulvalenes: overcrowded olefinic structure and chain length-dependent properties-Reference-Cited by-同舟云学术

Ring-expansion approach towards extended asymmetric benzopentafulvalenes: overcrowded olefinic structure and chain length-dependent properties

Published:2020 Issue:16 Volume:7 Page:2247-2254
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Wang Xinhao¹²³⁴,Zhang Zihong¹²³⁴,Guo Jing⁵⁶²³⁴,Liu Chunyan¹²³⁴,Hu Yuanyuan⁵⁶²³⁴,Xiao Huiping⁷⁸⁹⁴,Xie Sheng¹²³⁴^ORCID,Wu Jishan¹⁰¹¹¹²^ORCID,Zeng Zebing¹²³⁴^ORCID

Affiliation:

1. State Key Laboratory of Chemo/Biosensing and Chemometrics

2. Hunan University

3. Changsha 410082

4. P. R. China

5. Key Laboratory for Micro-Nano Optoelectronic Devices of Ministry of Education

6. School of Physics and Electronics

7. School of Materials Science and Engineering

8. Nanchang Hangkong University

9. Nanchang 330063

10. Department of Chemistry

11. National University of Singapore

12. Singapore

Abstract

A strain energy-induced ring-expansion is described to construct novel asymmetric benzopentafulvalenes precisely, which show chain length-dependent physical properties and air-stable ambipolar carrier transport.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Hunan Province

Ministry of Education - Singapore

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/QO/D0QO00602E

Reference54 articles.

1. D. Lenoir , P. J.Smith and J. F.Liebman , in Strained hydrocarbons , ed. H. Dodziuk , Wiley , Weinheim, Germany , 2009 ; ch. 3.1, p. 103