Steric effects of CN vacancies for boosting CO<sub>2</sub> electroreduction to CO with ultrahigh selectivity-Reference-Cited by-同舟云学术

Steric effects of CN vacancies for boosting CO₂ electroreduction to CO with ultrahigh selectivity

Published:2023 Issue:2 Volume:59 Page:203-206
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Zhang Qiang¹^ORCID,Wang Jianlin¹,Guo Fang¹,Zhou Yang²,He Ge³,Xu Junqiang¹^ORCID

Affiliation:

1. School of Chemistry & Chemical Engineering, Chongqing University of Technology, Chongqing 400054, P. R. China

2. The Analytical and Testing Center, Chongqing University, Chongqing 400044, P. R. China

3. College of Biomass Science and Engineering, Sichuan University, Chengdu 610065, China

Abstract

We have reported that the CN vacancies was obtained by H2 cold plasma bombardment. The steric effect of VCN can decrease the free energy barrier of *COOH and further crack into CO under low overpotential.

Funder

National Natural Science Foundation of China

Chongqing Municipal Education Commission

Chongqing University of Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D2CC05764F

Reference26 articles.

1. Lowering C−C coupling barriers for efficient electrochemical CO2 reduction to C2H4 by jointly engineering single Bi atoms and oxygen vacancies on CuO

2. Recent advances in MoS₂-based materials for electrocatalysis

3. High-Temperature Electrochemical Devices Based on Dense Ceramic Membranes for CO2 Conversion and Utilization

4. Efficient Electrochemical Reduction of CO 2 to HCOOH over Sub‐2 nm SnO 2 Quantum Wires with Exposed Grain Boundaries

5. Screening highly active perovskites for hydrogen-evolving reaction via unifying ionic electronegativity descriptor

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