The exemplary role of nanoconfinement in the proton transfer from acids to ammonia-Reference-Cited by-同舟云学术

The exemplary role of nanoconfinement in the proton transfer from acids to ammonia

Published:2017 Issue:30 Volume:19 Page:19869-19872
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Tripathy Manoj K.¹²³⁴^ORCID,Chandrakumar K. R. S.⁵²³⁴⁶^ORCID

Affiliation:

1. Research Reactor Services Division

2. Bhabha Atomic Research Centre

3. Mumbai 400085

4. India

5. Theoretical Chemistry Section

6. Homi Bhabha National Institute

Abstract

Proton transfer processes from mineral acids to bases are normally feasible in solution and they cannot spontaneously occur in the gas phase. Our results demonstrate that the remarkable aspect of reaction barrier crossing can be achieved by confining these systems in a suitable size of a nanocavity.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP03945J

Reference26 articles.

1. The rotational spectrum of 15N-ammonium chloride vapour: characterisation of the hydrogen-bonded dimer H3N...HCl

2. The nature of ammonium and methylammonium halides in the vapour phase: hydrogen bonding versus proton transfer

3. Proton transfer reaction of hydrogen chloride with ammonia: is it possible in the gas phase?

4. Ab Initio Investigation of Proton Transfer in Ammonia−Hydrogen Chloride and the Effect of Water Molecules in the Gas Phase

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