Copper-catalyzed asymmetric allylic C–H amination of alkenes using N-arylhydroxylamines-Reference-Cited by-同舟云学术

Copper-catalyzed asymmetric allylic C–H amination of alkenes using N-arylhydroxylamines

Published:2021 Issue:13 Volume:8 Page:3228-3237
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Murru Siva¹²³⁴⁵^ORCID,Mokar Bhanudas D.⁶⁷⁸⁵,Bista Ramesh¹²³⁴⁵,Harakat Dominique⁹¹⁰¹¹,Le Bras Jean⁹¹⁰¹¹,Fronczek Frank⁶¹²¹³⁵,Nicholas Kenneth M.¹⁴¹⁵⁵^ORCID,Srivastava Radhey S.⁶⁷⁸⁵^ORCID

Affiliation:

1. Chemistry Program

2. School of Sciences

3. University of Louisiana at Monroe

4. Louisiana 71209

5. USA

6. Department of Chemistry

7. University of Louisiana at Lafayette

8. Louisiana 70504

9. Institut de Chimie Moléculaire de Reims – UMR 7312 CNRS-Université de Reims Champagne-Ardenne UFR des Sciences Exactes et Naturelles

10. 51687 REIMS Cedex 2

11. France

12. Louisiana State University

13. Baton Rouge 70803

14. Department of Chemistry and Biochemistry

15. University of Oklahoma

Abstract

The first Cu-catalyzed asymmetric allylic C–H amination of alkenes with N-aryl hydroxylamines has been developed. Metal-complexes isolation, ESI-MS analysis and the DFT calculations provided key insights on mechanistic pathway.

Funder

National Science Foundation

National Institute of General Medical Sciences

Supercomputing Center for Education and Research, University of Oklahoma

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QO/D1QO00223F

Reference101 articles.

1. Iridium-Catalyzed Asymmetric Allylic Substitution Reactions