A deeper look into the photocycloreversion of a yellow diarylethene photoswitch: why is it so fast?
Author:
Affiliation:
1. Institute of Applied Radiation Chemistry
2. Lodz University of Technology
3. 93-590 Łódź
4. Poland
5. Institute of Physics
6. Łódź
Abstract
The DMT photoswitch features an efficient ring-opening reaction at a sub-picosecond timescale owing to a single-channel relaxation from the S1 state which leads to a conical intersection with the ground state.
Funder
Narodowe Centrum Nauki
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2020/CP/C9CP05452A
Reference32 articles.
1. Photochromism of Diarylethene Molecules and Crystals: Memories, Switches, and Actuators
2. Fluorescent Photoswitchable Diarylethenes for Biolabeling and Single-Molecule Localization Microscopies with Optical Superresolution
3. Controlling Biological Activity with Light: Diarylethene-Containing Cyclic Peptidomimetics
4. Light-Induced Switching of Tunable Single-Molecule Junctions
5. Reversible Photocontrol of Biological Systems by the Incorporation of Molecular Photoswitches
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