Azo-triazolide bis-cyclometalated Ir(iii) complexes via cyclization of 3-cyanodiarylformazanate ligands-Reference-Cited by-同舟云学术

Azo-triazolide bis-cyclometalated Ir(iii) complexes via cyclization of 3-cyanodiarylformazanate ligands

Published:2020 Issue:12 Volume:49 Page:3775-3785
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Mu Ge¹²³⁴,Wen Zhili¹²³⁴^ORCID,Wu Judy I-Chia¹²³⁴^ORCID,Teets Thomas S.¹²³⁴^ORCID

Affiliation:

1. University of Houston

2. Department of Chemistry

3. Houston

4. USA 77204-5003

Abstract

Sterically encumbered iridium-bound formazanate ligands undergo redox-neutral cyclization to form azo-triazolides, a new class of redox-active chelating ligand.

Funder

University of Houston

Welch Foundation

National Science Foundation

National Institute of General Medical Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/C9DT03914G

Reference67 articles.

1. Steric and Dynamic Parameters Influencing In Situ Cycloadditions to Form Triazole Inhibitors with Crystalline Acetylcholinesterase

2. “Click-fluors”: triazole-linked saccharide sensors

3. Azo-bridged triazoles: Green energetic materials

4. A Stepwise Huisgen Cycloaddition Process: Copper(I)-Catalyzed Regioselective “Ligation” of Azides and Terminal Alkynes

5. Azo-linked high-nitrogen energetic materials

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