PhICl2 is activated by chloride ions-Reference-Cited by-同舟云学术

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PhICl2 is activated by chloride ions

Published:2021 Issue:34 Volume:50 Page:11986-11991
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Tania ¹,Poynder Tiffany B.¹,Kaur Aishvaryadeep¹,Barwise Lachlan¹,Houston Sevan D.¹,Nair Akshay J.²,Clegg Jack K.²^ORCID,Wilson David J. D.¹^ORCID,Dutton Jason L.¹^ORCID

Affiliation:

1. Department of Chemistry and Physics, La Trobe University, Melbourne, Victoria, Australia

2. School of Chemistry and Molecular Biosciences, The University of Queensland, St Lucia, Queensland, 4072, Australia

Abstract

A study on the potential activating role of pyridine in the electrophilic chlorination of anisole by PhICl2 has led to the discovery that soluble sources of chloride ions activate PhICl2 in the reaction at catalytic loadings, greatly increasing the rate of chlorination.

Funder

La Trobe University

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT02565A

Reference31 articles.

1. Advances in Synthetic Applications of Hypervalent Iodine Compounds

2. Chemistry of Polyvalent Iodine

3. Hypervalent Iodine Reagents in High Valent Transition Metal Chemistry

4. Advances in Iodine(III)-Mediated Halogenations: A Versatile Tool to Explore New Reactivities and Selectivities

5. Dihaloiodoarenes: α,α-Dihalogenation of Phenylacetate Derivatives

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1. Recent Progress in Synthetic Applications of Hypervalent Iodine(III) Reagents;Chemical Reviews;2024-09-13

2. A decade of lessons in the activation of ArIL₂ species;Chemical Science;2024

3. Electrophilic activation of molecular bromine mediated by I(iii);Dalton Transactions;2023

4. On the potential intermediacy of PhIBr₂ as a brominating agent;Organic & Biomolecular Chemistry;2022

5. Kinetic study on the activation of PhICl₂ with Lewis bases for aromatic chlorination;Dalton Transactions;2022

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