Reactions of heteroallenes with cyclam-based Zr(iv) complexes-Reference-Cited by-同舟云学术

Reactions of heteroallenes with cyclam-based Zr(iv) complexes

Published:2015 Issue:3 Volume:44 Page:1441-1455
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Alves Luis G.¹²³⁴⁵,Madeira Filipe¹²³⁴⁵,Munhá Rui F.¹²³⁴⁵,Barroso Sónia¹²³⁴⁵^ORCID,Veiros Luis F.¹²³⁴⁵,Martins Ana M.¹²³⁴⁵

Affiliation:

1. Centro de Química Estrutural

2. Instituto Superior Técnico

3. Universidade de Lisboa

4. 1049-001 Lisboa

5. Portugal

Abstract

Reactions of heteroallenes with cyclam-based Zr(iv) complexes are described. The products obtained revealed the formation of ureate, thioureate, guanidinate or dithiocarbamate cyclam derivatives upon [2 + 2] cycloaddition of the Zr–N_amido bonds of the cyclam. DFT calculations clarified the reactivity patterns observed.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT02851A

Reference108 articles.

1. E. Negishi and J.-L.Montchamp, in Metallocenes: Synthesis, Reactivity, Applications, ed. A. Togni and R. L. Halterman, Wiley-VCH, New York, 1998, vol. 1, p. 241

2. Insertions of heterocumulenes into the M-C .sigma.-bonds of Cp*M(NO)(aryl)2 (M = molybdenum, tungsten) complexes

3. Insertion Reactions of Isocyanates, Isothiocyanates, and Carbon Disulfide into Mg−C Bonds of Polynuclear Aluminum−Magnesium Compounds: Synthesis, Characterization, and Crystal Structures

4. Mechanism of Insertion of Carbodiimides into the Zr−C Bonds of Zirconaaziridines. Formation of α-Amino Amidines

5. Cyclopentenone Formation by Regioselective Intermolecular Coupling of Trisubstituted Alkenes, Alkynes, and Isocyanates

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