Electrochemical sensing mechanism of ammonium ions over an Ag/TiO2 composite electrode modified by hematite

Author:

Zhang Shilin12345,Hu Jinqing2,Li Sam Fong Yau45ORCID,Lu Hongxiu2,Wang Gang2,Lu Chang2,Sarwar Muhammad Tariq136,Tang Aidong1236ORCID,Yang Huaming136

Affiliation:

1. Engineering Research Center of Nano-Geomaterials of Ministry of Education, China University of Geosciences, Wuhan 430074, P. R. China

2. College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China

3. Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan 430074, P. R. China

4. Department of Chemistry National University of Singapore, 3 Science Drive 3, Singapore 117543, Singapore

5. NUS Environmental Research Institute, National University of Singapore, T-Lab Building, 5A Engineering Drive 1, Singapore 117411, Singapore

6. Key Laboratory of Functional Geomaterials in China Nonmetallic Minerals Industry, China University of Geosciences, Wuhan 430074, P. R. China

Abstract

The rapid, accurate and highly sensitive detection of NH4+ under non-alkaline conditions is achieved by electrooxidizing NH4+ to hydrazine via H2O2 derived from the oxygen reduction reaction over a self-supporting Ag/Fe2O3/TiO2 sensor.

Funder

China Scholarship Council

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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