Tunable magnetic anisotropy in luminescent cyanido-bridged {Dy2Pt3} molecules incorporating heteroligand PtIV linkers

Author:

Puzan Agnieszka1ORCID,Zychowicz Mikolaj1ORCID,Wang Junhao2ORCID,Zakrzewski Jakub J.1ORCID,Reczyński Mateusz12ORCID,Ohkoshi Shin-ichi2ORCID,Chorazy Szymon1ORCID

Affiliation:

1. Faculty of Chemistry, Jagiellonian University, Gronostajowa 2, 30-386 Kraków, Poland

2. Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan

Abstract

The halogeno-cyanido PtIV complex was used as a metalloligand in emissive {DyIII2PtIV3} single-molecule magnets tuned by the solvent-dependent coordination geometry and alignment of Me3PO ligands.

Funder

Ministerstwo Nauki i Szkolnictwa Wyższego

Narodowe Centrum Nauki

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference97 articles.

1. C.Benelli and D.Gatteschi , Introduction to Molecular Magnetism: From Transition Metals to Lanthanides , Wiley-VCh , 2015

2. Molecular Magnetic Materials: Concepts and Applications , ed. B. Sieklucka and D. Pinkowicz , Wiley-VCh , 2016

3. Molecular magnetism: from chemical design to spin control in molecules, materials and devices

4. The fruitful introduction of chirality and control of absolute configurations in molecular magnets

5. Dynamic molecular crystals with switchable physical properties

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