Orthogonally deconstructable and depolymerizable polysilylethers <i>via</i> entropy-driven ring-opening metathesis polymerization-Reference-Cited by-同舟云学术

Orthogonally deconstructable and depolymerizable polysilylethers via entropy-driven ring-opening metathesis polymerization

Published:2022 Issue:61 Volume:58 Page:8496-8499
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Johnson Alayna M.¹^ORCID,Husted Keith E. L.¹^ORCID,Kilgallon Landon J.¹,Johnson Jeremiah A.¹^ORCID

Affiliation:

1. Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA 02139, USA

Abstract

The synthesis of low Tg polysilylethers via entropy-driven ring-opening metathesis polymerization is reported. These polymers can be depolymerized through olefin metathesis or deconstructed with acid or fluoride.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC02718F

Reference25 articles.

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3. A Practical and Highly Active Ruthenium-Based Catalyst that Effects the Cross Metathesis of Acrylonitrile

4. Ring opening metathesis polymerization (ROMP) of five- to eight-membered cyclic olefins: Computational, thermodynamic, and experimental approach

5. Modeling Ring-Chain Equilibria in Ring-Opening Polymerization of Cycloolefins

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