Highly 2,3-selective polymerization of phenylallene and its derivatives by vanadium complexes
Author:
Affiliation:
1. Department of Polymer Science and Engineering
2. School of Chemistry and Chemical Engineering
3. and Anhui Key Laboratory of Advanced Catalytic Materials and Reaction Engineering
4. Hefei University of Technology
5. People's Republic of China
Abstract
Allene polymerizations by vanadium complexes using various Al co-catalysts were carried out. All the vanadium complexes show moderate activity for phenylallene and high 2,3-selectivity (>99%).
Funder
National Natural Science Foundation of China
Natural Science Foundation of Anhui Province
Fundamental Research Funds for the Central Universities
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering
Link
http://pubs.rsc.org/en/content/articlepdf/2021/PY/D1PY00761K
Reference40 articles.
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3. Polymerization of 1,5-Hexadiene by Half-Titanocenes−MAO Catalyst Systems: Factors Affecting the Selectivity for the Favored Repeated 1,2-Insertion
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