Mechanism of the cooperative Si–H bond activation at Ru–S bonds-Reference-Cited by-同舟云学术

Mechanism of the cooperative Si–H bond activation at Ru–S bonds

Published:2015 Issue:7 Volume:6 Page:4324-4334
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Stahl Timo¹²³⁴,Hrobárik Peter¹²³⁴,Königs C. David F.¹²³⁴⁵,Ohki Yasuhiro⁵⁶⁷⁸⁹,Tatsumi Kazuyuki⁵⁶⁷⁸⁹,Kemper Sebastian¹²³⁴,Kaupp Martin¹²³⁴,Klare Hendrik F. T.¹²³⁴^ORCID,Oestreich Martin¹²³⁴^ORCID

Affiliation:

1. Institut für Chemie

2. Technische Universität Berlin

3. 10623 Berlin

4. Germany

5. Department of Chemistry

6. Graduate School of Science and Research Center for Materials Science

7. Nagoya University

8. Nagoya 464-8602

9. Japan

Abstract

The heterolytic splitting of hydrosilanes by ruthenium(ii) thiolates is illuminated by a combined spectroscopic, crystallographic, and computational analysis.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC01035G

Reference88 articles.

1. S. Rendler and M.Oestreich, in Modern Reduction Methods, ed. P. G. Andersson and I. J. Munslow, Wiley-VCH, Weinheim, 2008, ch. 8, pp. 183–207

2. Reactions of Hydrosilanes with Transition Metal Complexes and Characterization of the Products

3. Reactions of Hydrosilanes with Transition-Metal Complexes: Formation of Stable Transition-Metal Silyl Compounds